BISMUTH CITRATE USP

 Safety Data Sheet  
Emergency Telephone Number: CHEMTREC 1-800-424-9300   For Information call: DUDLEY 732-886-3100        
                DUDLEY CHEMICAL CORPORATION
                              125 Kenyon Drive
      				                    Lakewood, New Jersey 08701 
Effective Date: January 1, 2025
1. PRODUCT ID: CAS No.:  813-93-4  EC-No.: 212-390-1   Weight: 398.08.   Formula: BiC6H5O7. 

2. HAZARDS ID:   GHS:  Not a hazardous substance.

Potential Effects: Eye: May cause eye irritation.  Skin: May cause skin irritation   Ingestion: May cause irritation of the digestive tract. Inhalation: May cause respiratory tract irritation. Material may be irritating to mucous membranes and upper respiratory tract. Chronic Exposure:  Repeated or prolonged ingestion may cause a “bismuth line” black spots on the gums, foul breath, and salivation. 
2.3: Other Hazards: none

3. COMPOSITION / INFO ON INGREDIENTS:
Chemical Name                        CAS No.                            Percent                    Hazardous           
 Bismuth Citrate                       813-93-4                           ~50%                           No            

4. FIRST AID: Eyes:  Flush eyes with plenty of water as precaution.   Skin:  If contact, flush skin with plenty of soap & water.   Ingestion: If victim is conscious and alert water to rinse mouth.  Do NOT induce vomiting.  NEVER give anything by mouth to an unconscious person.  Inhalation:  Remove to fresh air.  If not breathing, give artificial respiration.  If breathing is difficult, give oxygen. Physician:  Treat symptomatically and supportively. 

5. FIRE FIGHTING: Info: Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH & full PPE. Irritating & highly toxic gases may be generated by thermal decomp/combustion. Extinguishing: Use water spray, 
carbon dioxide, dry chem powder, or alcohol-resistant foam. Hazards:  Carbon oxides, Bismuth oxides. Flash Pt: N/A Auto-ignition Temp: N/A. Explosion Limits: N/A

6. ACCIDENTAL RELEASE: Info: Use proper PPE as indicated in Section 8. Spills/Leaks: Sweep up and containerize 
for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal. Provide ventilation. 

7. HANDLING & STORAGE: Handling: Wash thoroughly after handling. Use adequate ventilation. Minimize dust generation & accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatibles. Protect against physical damage. 

8. EXPOSURE: facility storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. 
Chemical Name                     ACGIH                          NIOSH                  OSHA-Final PELs 
Bismuth Citrate                      None listed                  None listed             None listed

PPE: Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear protective gloves and clean body-covering clothing. 0.11mm nitrile Clothing: Wear appropriate protective clothing to prevent skin exposure. 
Respirators:  Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149.  Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

9. PHYSICAL & CHEM: Appearance: White. Odor: Odorless Melting Pt: 300° C (572° F) (dec) Solubility: Insoluble. 

10. STABILITY & REACTIVITY: Stability: Stable under normal temp/pressures. Avoid: Incompatibles. Incompatibilities: Oxidizing agents. Hazardous Decomp: see section 5

11. TOXICOLOGICAL INFO: RTECS#:  Not available.   LD50/LC50: CAS# 813-93-4:  Not available.
Carcinogencity:  CAS# 813-93-4: Not listed by ACGIH, IARC, NOISH, NTP, or OSHA.

12. ECOLOGICAL INFO: Environmental Fate & Toxicity:  No information available.

13. DISPOSAL CONSIDERATIONS: Chemical waste generator must determine whether a discarded chemical is classified as a hazardous waste. U.S. EPAQ guidelines for the classification determination are listed in 40 CFR parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed           RCRA U-Series: None listed.

14. TRANSPORT REGULATIONS: Not regulated

15. REGULATORY INFO: SARA 311/312 Hazards:  No SARA Hazards
SARA Section 302 Extremely Hazardous Substances: None of the chemicals in this product have RQ/TPQ
Section 313    No chemicals are reportable under Section 313
STATE CAS# 813-93-4 is not present on state lists from CA,  MA, MN,FL
Pa Right to Know:   Bismuth citrate  NJ Right to Know:  Bismuth citrate. 
California No Significant Risk Level:  None of the chemicals in this product are listed.

EUROPEAN/INTERNATIONAL REGULATIONS European Labeling in Accordance with EC Directives
WGK (Water Danger/Protection)CAS# 813-93-4:  Not available
Canada – DSL/NDSL: CAS# 813-93-4 is not listed on Canada’s DSL List
Canada – WHMIS: Not available. CAS# 813-93-4 is not listed on Canada’s Ingredient Disclosure List

16. DISCLAIMER INFO: DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this.  Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.