CHOCOLATE BROWN HT 
Safety Data Sheet
 Emergency Telephone Number: CHEMTREC 1-800-424-9300      For Information call: DUDLEY 732-886-3100                                                                           			DUDLEY CORPORATION        
        	        125 Kenyon Drive	
       Lakewood, New Jersey 08701
                                                                         Effective Date:  January 1, 2024
1. PRODUCT ID: Syn:  C.I. Food Brown #3; Brown HT  CAS No.: 4553-89-3  	
Weight: 652.57  	Chemical Formula:  C17H18N4Na2O9S2
2.HAZARDS ID: GHS Classification:	Not a hazardous substance or mixture.
HMIS Classification: Health hazard  1, Flammability   0,  Physical hazards   0			
NFPA Rating: Health hazard  1, Fire     0, Reactivity hazard   0

Potential Health Effects: Eye: Risk of serious damage to eyes.	Skin: Harmful in contact with skin. 
Ingestion: Harmful if swallowed. 		Inhalation: Harmful by inhalation. 
2.3: Other Hazards: none

3. COMPOSITION, INFO ON INGREDIENTS:
Chemical Name 		CAS No.		Percent		Hazardous
Chocolate Brown HT	224-924-0 	~   100		      No		

4. FIRST AID: Eyes: rinse with plenty of water Skin:. Rinse with plenty of soap & water Ingestion: Do not induce vomiting without medical advice. Rinse with water. Inhalation: Move to fresh air.  Physician: Treat symptomatically & supportively. 

5. FIRE FIGHTING: Info: wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH &  full PPE. Irritating & highly toxic gases may be generated by thermal decomp/combustion. Vapors may be heavier than air.  They can spread along the ground and collect in low or confined areas.  Runoff from fire control or dilution water may cause pollution. Hazards:  Carbon & nitrogen oxides. Extinguishing: Use water spray, dry chemical, chemical foam, or alcohol-resistant foam. Flash Pt: No data Auto-ignition Temp: N/A Explosion Limits: No data

6. ACCIDENTAL RELEASE: Spills/Leaks: Sweep up spilled substance carefully, then clean with water.  Do not flush away any residue with water. Use clean cotton cloth. Disposal: Incinerate in suitably designed equipment or in accordance with local regulations. – Wear PPE as required,

7. HANDLING & STORAGE: Handling: The usual precautions taken when handling dyes should be observed.  As the substance is an edible dye, not hazardous to water supply. Storage: Store in a cool dry place with good ventilation in a tightly sealed container. Use self-contained breathing apparatus. 

8. EXPOSURE CONTROLS, PPE: Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility/safety shower. Use adequate ventilation to keep airborne concentrations low.
Chemical Name			ACGIH		NIOSH		OSHA – Final/Vacated PEL’s
Chocolate Brown HT 		None listed	None listed	None listed 

PPE: Eyes: Protective glasses may be used. Skin: Protective Rubber gloves may be used.  Wash hands with soap and water before and after using product. Clothing:  Protective clothing may be used.
Respirators: May be used (In case of dust formation, particle filter e.g. DIN 3181-21)

9. PHYSICAL & CHEM: Appearance:  Reddish Brown powder Solubility:  180 gms/litre  Density: 0.70  

10. STABILITY & REACTIVITY: Stability:. Stable under normal conditions. Sensitive to moist air. Avoid:  High temperatures, storage under damp atmosphere  Incompatibilities:  Strong reducing agents, Decolorizing agents, Strong acids & alkalies. Hazardous Decomp Products:  see section 5

11. TOXICOLOGICAL INFO: LD50; Oral; 6000-10000 mg/kg body weight,  LD50 Intraperitoneal; 3800-5000 mg/kg body weight, Other Studies: Acceptable Daily Intake: JECFA: 0-2.5 mg/kg body weight  EEC: 0-2.5 mg/kg body weight

12. ECOLOGICAL INFO: No data

13. DISPOSAL CONSIDERATIONS: Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. 

14. TRANSPORT INFO: Not regulated.

15. REGULATORY INFO: SARA 311/312: None SARA Section 302 None of the chemicals in this product have a TPQ.
Section 313  No chemicals are reportable under Section 313. 
STATE CAS# 4553-89-3 is not present on state lists from CA, MN, MA, FL. 
PA & NJ Right to Know:	Chocolate Brown HT  CAS#4553-89-3
California Prop.65 components: None of the chemicals are known to cause cancer, birth defects, or any other reproductive harm.

EUROPEAN/INTERNATIONAL REGULATIONS European Labeling in Accordance with EC Directives 
WGK (Water Danger/Protection) CAS# 4553-89-3:  No information available. 
Canada - DSL/NDSL CAS# 4553-89-3  is not listed on Canada’s DSL List.   Canada – WHMIS  WHMIS:  Not available.
CAS# 4553-89-3 is not listed on Canada’s Ingredient Disclosure List. 

16. DISCLAIMER INFO: DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this.  Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.