METHYL 3-HYDROXYBENZOATE

Safety Data Sheet
Emergency Telephone Number: CHEMTREC 1-800-424-9300       For Information call: DUDLEY 732-886-3100       
      DUDLEY CORPORATION
           	   125 Kenyon Drive
       				         	   Lakewood, New Jersey 08701
Effective Date: January 1, 2025
1. PRODUCT: CAS No.: 19438-10-9 E-C No.:243-071-5 Weight:  152.15g/mol 	Formula: C8H8O3

2. HAZARDS: GHS Classification: Acute toxicity, Oral (Category 4)	Skin irritation (Category 2)
Eye irritation (Category 2A)	Specific target organ toxicity - single exposure (Category 3)
 Pictogram: 				
Signal Word:         WARNING
HAZARD STATEMENT: H302: Harmful if swallowed	H319: Causes serious eye irritation.	H315: Causes skin irritation 	H335: May cause respiratory irritation	
PRECAUTIONARY STATEMENT: P261: Avoid breathing dust/spray/ fume/gas/ mist/ vapors. P264: wash skin thoroughly after handling	P270: Do not drink, eat, smoke, when using this product. P271: Use only outdoors or in well-ventilated area. P405: Store locked up.  P330: Rinse mouth P280: Wear protective gloves/eye & face protection P301 + P302 + P352: If on skin gently wash with plenty of soap & water. P304 + P340: If inhaled: remove to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: If in Eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present & easy to do so. Continue Rinsing. P312: Call Poison Center or doctor/physician if you feel unwell P321: Specific treatment (see supplemental first aid instructions) P332 + P313: If skin irritation occurs: consult physician P337+ P313: If eye irritation occurs: consult physician P362: Take off contaminated clothing and wash before reuse. P403 + P233: Store in a well ventilated place. Keep container tightly closed.
P501: Dispose of contents/container to an approved waste disposal plant.

HMIS Class: Health hazard  2, Flammability   0,  Physical hazards   0			
NFPA Rating: Health hazard  2, Fire     0, Reactivity hazard   0
2.3: Other Hazards: none

3. COMPOSITION / INFO ON INGREDIENTS: 
Chemical 			 CAS No.	 	Percent		
Methyl 3-hydroxybenzoate	                19438-10-9               98%                  

4. FIRST AID: Eyes: rinse immediately with plenty of water for 15 min. and seek medical advice. Skin: Rinse with plenty of soap & water and seek medical advice. Ingestion: Do not induce vomiting without medical advice. Rinse with water. Consult physician. Inhalation: Move to fresh air.  Physician: Treat symptomatically & supportively. 

5. FIRE FIGHTING: Info: wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH & full PPE. Irritating/toxic gases may be generated by thermal decomp/combustion. Hazards:  Carbon oxides. Extinguishing:  Use water spray, dry chem, carbon dioxide, or alcohol-resistant foam. Flash Pt: N/A. Auto-ignition Temp: N/A. Explosion Limits: N/A. 

6. ACCIDENTAL RELEASE: Info: Use proper PPE as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section.  Avoid generating dusty conditions. Provide ventilation.  

7. HANDLING & STORAGE: Handling: Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use only in a chemical fume hood. Wash clothing before reuse. Storage: Store in a cool, dry place. Store in a tightly closed container. 

8. EXPOSURE: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. 
Chemical 	                      ACGIH               NIOSH                      OSHA - Final / Vacated PELs 
Methyl 3-Hydroxybenzoate       None listed           None listed                 None listed. 

PPE:  Eyes: Wear appropriate protective eyeglasses for chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR 1910.133 or European Standard en166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirators when necessary. 

9. PHYSICAL & CHEM: Appearance: White-off-white/beige powder. Boiling Pt: 280-281˚C at 945 hPa (709 mmHg) Melting Pt: 71-73˚C Partition coefficient: n-octanol/water: low Pow: 1.78

10. STABILITY & REACTIVITY: Stability: Stable at room temp in closed containers under normal storage & handling. Avoid: Incompatibles, excess heat, exposure to moist air or water. Incompatibilities: Oxidizing agents, strong bases. Haz Decomp: see section 5

11. TOXIC INFO: RTECS#: unlisted. LD50/LC50: N/A Carcinogenicity: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA. 

12. ECOLOGICAL INFO: Environmental Fate/ Toxicity:  No information available.

13. DISPOSAL CONSIDERATIONS: Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR
Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification. RCRA P-Series: None listed. RCRA U-Series: None listed. 

14. TRANSPORT REGULATIONS: Not regulated.

15. REGULATORY INFO: SARA 311/312:  Acute Health Hazard
Section 302 (RQ) & Section 302 (TPQ) None of the chemicals in this material/products have a RQ, TPQ. 
Section 313 No chemicals are reportable under Section 313. 
STATE CAS# 19438-10-9 is not present on state lists from CA, MN, MA, FL. 
Pa & NJ Right to Know:	Methyl 3-hydroxybenzoate  CAS#19438-10-9
California Prop.65 components: None of the chemicals are known to cause cancer, birth defects, or any other reproductive harm.

EUROPEAN/INTERNATIONAL REGULATIONS European Labeling in Accordance with EC Directives 
Hazard Symbols: XI. 

WGK (Water Danger/Protection) CAS# 19438-10-9: No information available. 
Canada -DSL/NDSL:  None of the chemicals in this product are listed on the DSL or NDSL list. 
Canada - WHMIS This product has a WHMIS classification of D2B. 

16. DISCLAIMER INFO: DUDLEY CORPORATION provides the information herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this.  Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. DUDLEY CORPORATION makes no representations or warranties, either expressed or implied, including without limitation and warranties of merchantability, fitness for a particular purpose with respect to the information set forth herein or to the product to which the information refers. Accordingly, DUDLEY CORPORATION will not be responsible for damages resulting from the use of or reliance upon this information.